Aluminum from clay: Difference between revisions
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Kaolin clay is composed of aluminum and silicon (Si2Al2O5(OH)4). | Kaolin clay is composed of aluminum and silicon (Si2Al2O5(OH)4). Reduction of Kaolin would then result in an aluminum/silicon alloy. In practice, carbides (usually SiC) resist further reduction except at very high temperatures (2050 degrees celcius). Thus, the smelted product is likely some aluminum-rich alloy with various highly refractory simple and complex carbides. | ||
Parent material is reduced | Parent material is reduced carbothermically, that is, it is reduced in the presence of carbon and the absence of oxygen at high temperatures. The carbon is oxidized to produce carbon mon- and di-oxide and the metal oxides are reduced. | ||
The paper [http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6V2S-4PF0X6V-1&_user=521384&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_acct=C000059563&_version=1&_urlVersion=0&_userid=521384&md5=beeacd8e14dee1a7cb0059b6bb739790 Carbothermal reduction of alumina] by m.halmann (at) weizmann.ac.il describes the carbothermic reduction of alumina rich material in an atmosphere of methane gas at high temperatures. Such temperatures could be produced with a point focusing solar collector. | |||
Page 66 in this online book talks about a plant in the Ukraine that does smelt kaolin into an Aluminum/silicon alloy: [http://books.google.com/books?id=XlmAKOjvnrgC&pg=PA66&lpg=PA66&dq=reduction+kaolin+aluminum&source=web&ots=2vF1okG5iX&sig=oh_J4JdI6XQDxZ68-j2i-b767Tw&hl=en#PPA65,M1 the handbook of aluminum] | |||
By George E Totten, D Scott MacKenzie | By George E Totten, D Scott MacKenzie | ||
At temperatures below 2000 degrees Celcius, I assume | At temperatures below 2000 degrees Celcius, I assume aluminum metal may be separated from silicon carbide (SiC). | ||
[[Category:Materials]] | [[Category:Materials]] | ||
Revision as of 15:05, 31 December 2010
Kaolin clay is composed of aluminum and silicon (Si2Al2O5(OH)4). Reduction of Kaolin would then result in an aluminum/silicon alloy. In practice, carbides (usually SiC) resist further reduction except at very high temperatures (2050 degrees celcius). Thus, the smelted product is likely some aluminum-rich alloy with various highly refractory simple and complex carbides.
Parent material is reduced carbothermically, that is, it is reduced in the presence of carbon and the absence of oxygen at high temperatures. The carbon is oxidized to produce carbon mon- and di-oxide and the metal oxides are reduced.
The paper Carbothermal reduction of alumina by m.halmann (at) weizmann.ac.il describes the carbothermic reduction of alumina rich material in an atmosphere of methane gas at high temperatures. Such temperatures could be produced with a point focusing solar collector.
Page 66 in this online book talks about a plant in the Ukraine that does smelt kaolin into an Aluminum/silicon alloy: the handbook of aluminum By George E Totten, D Scott MacKenzie
At temperatures below 2000 degrees Celcius, I assume aluminum metal may be separated from silicon carbide (SiC).