Supercritical Carbon Dioxide
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Basics
- Carbon Dioxide held above the Critical Point
- Here (and other Supercritical Fluids ) it behaves essentially as both a Liquid and a Gas
- It can be abbreviated as sCO2
Uses
Blowing Agent
- Involves dissolving sCO2 into the material, then rapidly depressurizing it to form a foam
- Need to look into this further for more specific details
Chemical Synthesis
- Need to look into this for specifics, but essentially using CO2 as the solvent for the reaction
- Of interest to the Pharmaceutical Industry, as the Product may be "precipitated" by expanding the mixture out of a nozzle, leaving a fine dry product akin to Spray Drying
Supercritical Fluid Chromatography
- Can be used for Analytic Chemistry, or in Simulated Moving Bed Chromatography at an industrial scale for purification/separation of desirable (or in the case of Decaffeination etc, undesirable) Compounds
Dry Cleaning
- Unlike other solvents, sCO2 has virtually no toxicity (short of it being an Asphyxiant Hazard ) so Disposal/Handling concerns are far less
Extraction
- Supercritical fluid extraction is very common in the Essential Oil Industry (for Fragrances / Food Additives ) (
And also in the Cannabis Industry for High Value High Purity Oils/Resins/Waxes) - It is effective, and also has little risk of contamination since simply depressurizing the mixture separates out the CO2 (which can then be collected and recycled)
- Main issue is initial cost of equipment
- It is also used for Decaffeination
As a Working Fluid
- It can be used as a Refrigerant , or as a Working Fluid in a Rankine Cycle (Although using Hydrocarbons in the Organic Rankine Cycle may be of more interest, pending a proper Decision Making Matrix or similar investigation as per the relevant OSE Specifications )
- It has the advantage over Butane and other similar proposed hydrocarbons in that it is not flammable
- The Allam-Fetvedt Cycle is a novel Power Generation system utilizing Oxy-Fuel Combustion in an all Supercritical Carbon Dioxide Atmosphere
Desorption of Spent Granulated Activated Carbon
- As per This 2024 Paper in “Chemosphere” Titled “ Regeneration of PFAS-laden granular activated carbon by modified supercritical CO2 extraction” sCO2 can be used to desorb PFAS (also other contaminants, albeit citation needed) from Spent Granulated Activated Carbon
Internal Links
External Links
- The Wikipedia Page on Supercritical Carbon Dioxide
- A 2012 Paper Titled "Supercritical fluid simulated moving bed chromatography for the separation of ethyl linoleate and ethyl oleate"
- A Video by the YouTube Channel "extraktLAB" Titled "How To Do Supercritical CO2 Extraction" ( ~2 Minute Watch )
- A Video by the YouTube Channel "Applied Science" Titled "A close look at supercritical carbon dioxide CO2" ( ~8 Minute Watch )
- A Video by the YouTube Channel "Applied Science" Titled "Caffeine extraction from green coffee with supercritical CO2" ( ~10 Minute Watch )
- A Video by the YouTube Channel "Applied Science" Titled "Supercritical CO2 extraction of cinnamon, coffee, and vanilla with dry ice " ( ~6 Minute Watch )
- A Video by the YouTube Channel "Applied Science" Titled "Custom supercritical CO2 chamber with easy-to-use lid clamp" ( ~7 Minute Watch )
- A Video by the YouTube Channel "Applied Science" Titled "Effect of long-term high pressure CO2 on acrylic" ( ~2 Minute Watch )
- Seems the Acrylic is not viable for long term / non-educational demo use
- A Video by the YouTube Channel "Vidya-mitra' Titled "Supercritical fluid extraction: principle and applications (FT)" (A 30 Minute Presentation by Dr. Richa Singh from the Indian Council of Agricultural Research-National Dairy Research Institute (ICAR-NDRI) )